Staudinger–Vilarassa reaction versus Huisgen reaction for the control of surface hydrophobicity and water adhesion |
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| Authors: | Guilhem Godeau Jessica N'Na Emna El Kout Rawia Ben Trad Thierry Darmanin Mejda El Kateb Mohammed Beji Frédéric Guittard |
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| Affiliation: | 1. CNRS, LPMC, UMR 7336, University of Nice Sophia Antipolis, Nice, France;2. Institut supérieur des études préparatoires en biologie et géologie, La Soukra, Tunisie;3. Institut préparatoire aux études d'ingénieurs de Tunis, Tunis university, Tunisie |
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| Abstract: | Surface modifications are keys for a great number of applications. In order to perfectly control the surface properties, it is important to control the modification pathways. Two general pathways can be described in order to introduce modification on surfaces: the post‐strategies and the ante‐strategies. In this work, we focus on the comparison between the Huisgen and the Staudinger–Vilarrasa reaction for both post‐surface and ante‐surface modifications. Here, we focused on the possibility to use both two reactions to obtain superhydrophobic and oleophobic properties. This work includes monomer synthesis, surface modifications with alkyl, aryl or perfluoroalkyl chain. Copyright © 2016 John Wiley & Sons, Ltd. |
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| Keywords: | click chemistry functionalization Huisgen reaction nanostructures superhydrophobic |
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