| 杂环化合物的红外多光子解离机理的研究 |
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| 引用本文： | 安新跃,郭用猷.杂环化合物的红外多光子解离机理的研究[J].高等学校化学学报,1990,11(5):501-505. |
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| 作者姓名： | 安新跃 郭用猷 |
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| 作者单位： | 山东大学化学系
(安新跃，郭用猷，顾月姝，刘传朴，侯正林)，山东大学化学系(印永嘉) |
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| 摘 要： | 采用TEA CO_2激光器研究了1,4-二氧六环、吡咯烷和噻吩等杂环化合物的红外多光子解离过程,探讨了解离机理,给出解离率与激光能流的关系。解离阈值分别为0.85、1.0、1.5J/cm~(-2)。
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| 关 键 词： | 二氧六环 吡咯烷 噻吩 光化学 |
IRMPD Mechanism Study of Heterocyclic Compounds |
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| An Xinyue,Guo Yongyou,Gu Yueshu,Liu Chuanpu,Hou Zhenglin,Yin Yongjia.IRMPD Mechanism Study of Heterocyclic Compounds[J].Chemical Research In Chinese Universities,1990,11(5):501-505. |
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| Authors: | An Xinyue Guo Yongyou Gu Yueshu Liu Chuanpu Hou Zhenglin Yin Yongjia |
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| Abstract: | The infrared multiphoton dissociation (IRMPD) of 1,4-dioxane, pyrrolidine and thiophene were studied with TEA COz laser. The mechanism involving breakage of carbon and heteroatom bonds were explored. The dependence of dissociation yield on laser energy was obtained. The laser dissociation threshold energy for dioxane, pyrrolidine and thiophene are 0. 85, 1.0 and 1. 5 J/cm2 respectively. |
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| Keywords: | The infrared multiphoton dissociation 1 4-Dioxane Pyrrolidine Thiophene |
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