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Monooxygenase activity of immobilized iron(III) porphyrins |
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| Authors: | G G Beskova V D Sokolovskii N B Shitova and V A Semikolenov |
| Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
| Abstract: | New silica-immobilized iron(III) porphyrin systems possessing monooxygenase activity in aniline oxidation to p-aminophenol, have been found. The catalytic activity depends on both the porphyrin structure and coordination by an axial ligand. The maximum activity in this reaction is observed for imidazol-coordinated hemin. The hydroxylation in the above system is shown to follow a non-radical mechanism.
This term refers to catalysis with the formation of monooxygenated products using dioxygen oxidants |
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