Copolymerization of acetylene with ethylene in the presence of dibenzenetitanium(0) |
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| Authors: | Kvashina E. F. Petrova G. N. Belov G. P. Roshchupkina O. S. Efimov O. N. |
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| Affiliation: | (1) Russian Academy of Sciences, Institute of Problems of Chemical Physics, 142432 Chernogolovka, Moscow Region, Russian Federation |
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| Abstract: | The interaction between acetylene and dibenzenetitanium(0) at a room temperature results in the acetylene polymerization and its reduction to ethylene, ethane, and methane at the expense of H atoms of the acetylene molecule. The catalytically active species capable of copolymerizing acetylene with ethylene that are formed during the reaction or are added into the system originate from the interaction of dibenzenetitanium(0) with acetylene. |
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| Keywords: | dibenzenetitanium(0) acetylene ethylene reduction copolymerization oxidative addition |
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