Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant |
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Authors: | Hövelmann Claas H Streuff Jan Brelot Lydia Muñiz Kilian |
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Affiliation: | Institut de Chimie, UMR 7177, Université Louis Pasteur, Strasbourg Cedex, France. |
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Abstract: | Palladium catalysed intramolecular guanidine transfer to alkenes can be accomplished with copper chloride as the oxidant to give bicyclic guanidines with complete selectivity and in high yields. |
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