| 4-(4-叔丁基苯氧基)-钒氧酞菁薄膜的拉曼散射及其表面形貌网络同步性 |
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| 引用本文： | 张茜,张能,张兆春.4-(4-叔丁基苯氧基)-钒氧酞菁薄膜的拉曼散射及其表面形貌网络同步性[J].光谱实验室,2010,27(2):402-407. |
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| 作者姓名： | 张茜 张能 张兆春 |
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| 作者单位： | 上海大学材料科学与工程学院,上海市延长路149号,200072 |
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| 基金项目： | 上海大学大学生创新实验项目(CXSJ08-066) |
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| 摘 要： | 利用溶液浇铸法,将4-(4-叔丁基苯氧基)-钒氧酞菁(44VOPc)分别沉积在石英和纳米磷化镓(nano-GaP)薄膜表面,制备44VOPc薄膜和nano-GaP/44VOPc复合薄膜。拉曼光谱分析结果表明,在完全相同的光散射测试条件下,44VOPc薄膜的光散射强度普遍高于nano-GaP/44VOPc复合薄膜。应用复杂网络动力学理论,通过构建薄膜表面形貌复杂网络,对2种薄膜拉曼散射强度之间的差异进行对比分析。表面形貌复杂网络的节点可以视为分子的集合体,而每一个节点又可以作为一个振子。由复杂网络同步性原理可知,振子之间在耦合振动过程中的同步性越好,对应系统的拉曼散射强度越大。
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| 关 键 词： | 4-（4-叔丁基苯氧基）-钒氧酞菁 拉曼散射 表面形貌 复杂网络 同步性 |
Raman Scattering and Surface Morphology Network Synchronization of 4- (4-Tertbutylphenoxy)-Vanadylphthalocyanine Films |
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| Zhang Qian,Zhang Neng,Zhang Zhao-Chun.Raman Scattering and Surface Morphology Network Synchronization of 4- (4-Tertbutylphenoxy)-Vanadylphthalocyanine Films[J].Chinese Journal of Spectroscopy Laboratory,2010,27(2):402-407. |
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| Authors: | Zhang Qian Zhang Neng Zhang Zhao-Chun |
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| Institution: | School of Materials Science and Engineering;Shanghai University;Shanghai 200072;P.R.China |
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| Abstract: | Using solution casting method,4-(4-tertbutylphenoxy)-vanadyl phthalocyanine(44VOPc) was deposited on the surface of quartz glass or gallium phosphide nanoparticulate film(nano-GaP).The scattering intensity of the 44VOPc film is generally higher than that of the 44VOPc/nano-GaP composite film.In order to explain the difference of Raman scattering intensity between 44VOPc film and 44VOPc/nano-GaP composite film,the surface morphology complex networks were constructed.Each node of the surface morphology comple... |
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| Keywords: | 4-(4-Tertbutylphenoxy)-Vanadyl Phthaloeyanine Raman Scattering Surface Morphology Complex Network Synchronization |
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