Adsorption of 1-heptanol on bismuth single-crystal plane electrodes |
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Authors: | Alar Jänes Peep Miidla Enn Lust |
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Institution: | 1.Institute of Physical Chemistry, University of Tartu, 2 Jakobi Street, 51014 Tartu, Estonia,;2.Institute of Applied Mathematics, University of Tartu, 2 Liivi Street, 50409 Tartu, Estonia, |
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Abstract: | Cyclic voltammetry, impedance and chronocoulometry have been employed for the quantitative study of 1-heptanol (1-HepOH)
adsorption on the bismuth single-crystal plane|aqueous Na2SO4 solution interface. The adsorption isotherms, Gibbs energies of adsorption,
, the limiting surface excess, Γmax, and other adsorption parameters have been determined. The adsorption of 1-HepOH on Bi single-crystal planes is mainly physical
and is limited by the rate of diffusion of organic molecules to the electrode surface. Comparison of the adsorption data for
1-HepOH with other alcohols shows that the adsorption characteristics depend on the structure of the hydrocarbon chain. The
adsorption activity of adsorbates at the bismuth|solution interface increases in the sequence 1-propanol<1-butanol<1-pentanol<1-hexanol<1-heptanol
as the adsorption activity at the air|solution interface increases. For all the compounds studied, the adsorption activity
increases in the sequence of planes as
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