A unique cyanide-bridged three-dimensional (3-D) copper(II)-copper(I) mixed-valence polymer containing 1-D water tapes with cyclic pentamer units |
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Authors: | Zheng Ji-Min Batten Stuart R Du Miao |
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Affiliation: | Department of Chemistry, Nankai University, Tianjin, P. R. China. |
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Abstract: | A unique cyano-bridged copper(II)-copper(I) mixed-valence polymer, {[Cu(3)(CN)(4)(H(2)O)(3)](H(2)O)(2)}(n) (1), has been prepared and structurally determined by X-ray diffraction. The cyanide anions with (mu(2),eta(2)) and (mu(3),eta(2)) bridging modes connect the copper centers into a complicated zeolite-like 3-D network. Of further interest, coordinated and lattice water molecules in this structure form 1-D hydrogen-bonded water tapes consisting of linked cyclic pentamer clusters. |
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