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Evaluation of structural and electrochemical properties of the MnSb–Li system as anode for Li-ion batteries |
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| Authors: | Costana Mihaela Ionica-Bousquet Manfred Womes Pierre-Emmanuel Lippens Josette Olivier-Fourcade Bernard Ducourant Alan V Chadwick |
| Institution: | (1) LAMMI (CNRS UMR 5072), Université Montpellier II, CC 015, Place E. Bataillon, Montpellier Cedex 5, 34095, France;(2) Functional Materials Group, School of Physical Sciences, University of Kent, Canterbury, Kent CT2 7NR, UK |
| Abstract: | The electrochemical reaction mechanisms between lithium and cystalline MnSb are investigated by X-ray diffraction, 121Sb Mössbauer spectroscopy, and X-ray absorption spectroscopy (XAS). The analysis of the experimental data at different depths of the electrochemical discharge process reveals a complex reaction mechanism comprising two steps. The main reaction of the first step corresponds to the dispersion of lithium in the MnSb matrix with formation of the intermediate compound LiMnSb. The second step corresponds to a Li–Sb alloying process with formation of Li3Sb. |
| Keywords: | intermetallics lithium reaction mechanism 121Sb M?ssbauer spectroscopy |
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