Oxidation of α-methylstyrene on an MCM-22 encapsulated (<Emphasis Type="Italic">R,R</Emphasis>)-(?)-<Emphasis Type="Italic">N,N′</Emphasis>-bis(3,5-di-<Emphasis Type="Italic">tert</Emphasis>-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) catalyst |
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Authors: | Krisztián Bogár |
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Institution: | (1) Department of Organic Chemistry, University of Szeged, Dóm tér 8, 6720 Szeged, Hungary;(2) Arrhenius Laboratory, Department of Organic Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden |
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Abstract: | (R, R)-(−)-N, N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) was encapsulated into MCM-22 using the zeolite synthesis method. The
encapsulated catalyst proved to be active in the oxidation of α-methylstyrene with NaOCl with higher specific activity than
the homogeneous catalyst. At the same time, this encapsulated catalyst was completely inactive in the hydrolytic kinetic resolution
of racemic styrene oxide. This observation is in a good correlation with the assumption of the cooperative bimetallic mechanism
proposed by Annis and Jacobsen. |
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Keywords: | Oxidation α -methylstyrene MCM-22 encapsulation (R R)-(− )-N N′ -bis(3 5-di-tert-butylsalicylidene)-1 2-cyclohexanediaminocobalt(II) |
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