| 丙烯腈和甲基丙烯酸酯基团转移共聚的竞聚率 |
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| 引用本文： | 邹友思,郭金全.丙烯腈和甲基丙烯酸酯基团转移共聚的竞聚率[J].高等学校化学学报,1996,17(7):1162-1163. |
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| 作者姓名： | 邹友思 郭金全 |
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| 作者单位： | 厦门大学化工系 |
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| 摘 要： | 丙烯腈和甲基丙烯酸酯基团转移共聚的竞聚率邹友思，郭金全，兰涛，戴李宗，潘容华（厦门大学化工系，厦门，３６１００５）关键词基团转移共聚．竞聚率．丙烯腈．甲基丙烯酸酯近年来对基团转移共聚竞聚率的研究较活跃［１～３］，一般认为甲基丙烯酸酯和丙烯酸酯两类单体...
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| 关 键 词： | 基团转移共聚 竞聚率 丙烯腈 甲基丙烯酸酯 |
The Reactivity Ratios of Group Transfer Copolymerization of Acrylonitrile with Methacrylates |
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| ZOU You-Si,GUO Jin-Quan,LAN Tao,DAI Li-Zong,PAN Rong-Hua.The Reactivity Ratios of Group Transfer Copolymerization of Acrylonitrile with Methacrylates[J].Chemical Research In Chinese Universities,1996,17(7):1162-1163. |
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| Authors: | ZOU You-Si GUO Jin-Quan LAN Tao DAI Li-Zong PAN Rong-Hua |
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| Abstract: | Random copolymerization have been performed for three binary systems using 1methoxy-2-methyl-1-trimethylsilyloxy propene(initiator)and tetrabutvlammonium bibenzoate(catalyst) in tetrahydrofutran solution. The copolymer compositions were determined by elementary analysis for nitrogen and the results evaluated by the Kelen-Tudos method.The monomer pairs concerned are (1)acrylonitrile(AN)and methyl methacrylate(MMA),(2)AN and ethyl methacrylate(EMA),(3)AN and butyl methacrylate (BMA). The reactivity ratios determined in this study are:(1)rAN=10.22, rMMA=0.07;(2)rAN=5068,rEMA=0.16;(30rAN=8.59,RBMA=0.09. |
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| Keywords: | Group transfer polymerization Reactivity ratio Acrylonitrile Methylmethacrylate |
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