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Hypervirial theorems and symmetry
Authors:Saul T. Epstein
Affiliation:(1) Physics Department, University of Wisconsin, 53706 Madison, Wisconsin, USA
Abstract:It is pointed out that to ensure that an optimal variational wave function PSgr having a certain symmetry satisfies the hypervirial theorem forW, it is sufficient thatiSWPSgr, whereS is the projector onto the symmetry type in question, be a possible variation of PSgr. Application is made to the tensor hypervirial theorem for atoms.
Keywords:Hypervirial theorem  Symmetry
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