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网状玻璃碳光谱电化学池的制作及应用
引用本文:瞿文川,朱世民,陈洪渊.网状玻璃碳光谱电化学池的制作及应用[J].分析化学,1993(5).
作者姓名:瞿文川  朱世民  陈洪渊
作者单位:南京大学化学系,南京大学化学系,南京大学化学系 南京 210008,南京 210008,南京 210008
摘    要:制作了一种以网状玻璃碳为工作电极的光谱电化学池,并介绍了对网状玻璃碳电极的处理方法。选用铁氰化钾-亚铁氰化钾体系,对其式量电位(E°′)、反应电子数(n)和扩散系数(D_R)进行了测定,取得较为满意的结果。

关 键 词:光谱电化学池  亚铁氰化钾  铁氰化钾  网状玻璃碳

Preparation and Application of Reticulated Vitreous Carbon Spectroelectrochemical Cell
Qu Wenchuan,Zhu Shimin,Chen Hongyuan.Preparation and Application of Reticulated Vitreous Carbon Spectroelectrochemical Cell[J].Chinese Journal of Analytical Chemistry,1993(5).
Authors:Qu Wenchuan  Zhu Shimin  Chen Hongyuan
Abstract:The spectroelectrochemical cell including a reticulated vitreous carbon working electrode has been preparated,and the treatment method for working electrode has been described. The system of ferrocyanide-ferricyanide is selected to characterize the properties of the cell. The Eo',n and DR values of system are determined by the cell. The result shows that the values fit and close to the references.
Keywords:Spectroelectrochemical cell  Reticulated vitreous carbon  Ferrocyanide  Ferricyanide    
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