Facile Access to 3-Alkyl-Substituted 3-Hydroperoxy-2,4-pyrrolidinediones Using Manganese(III)-Catalyzed Aerobic Oxidation |
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| Authors: | M Aminul Haque |
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| Institution: | Department of Chemistry, Graduate School of Science and Technology , Kumamoto University , Kumamoto , Japan |
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| Abstract: | Abstract 3-Alkyl-substituted 2,4-pyrrolidinediones were directly oxidized under very mild manganese(III)-catalyzed aerobic oxidation conditions to give the corresponding 3-hydroperoxy-2,4-pyrrolidinediones in quantitative yields. The scope and limitations for the synthesis of the hydroperoxyprrolidinediones are described. |
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| Keywords: | Aerobic oxidation catalytic oxidation hydroperoxidation hydroperoxypyrrolidinediones manganese(III) acetate 2 4-pyrrolidinediones |
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