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Catalytic carbopalladation of ω-methylenebicyclo[n.1.0]alkanes |
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| Authors: | William A Donaldson Christine A Brodt |
| Institution: | Department of Chemistry, Marquette University, Milwaukee, Wisconsin 53233 U.S.A. |
| Abstract: | ω-Methylenebicyclon.1.0]alkanes undergo carbopalladation via cleavage of the C(1)---C(2) cyclopropane bond. The resultant σ-butenyl complexes decompose via β-hydride elimination to afford the 1-cycloalkenylstyrene products. |
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