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Heterogeneously catalyzed synthesis of primary amides directly from primary alcohols and aqueous ammonia
Authors:Yamaguchi Kazuya  Kobayashi Hiroaki  Oishi Takamichi  Mizuno Noritaka
Affiliation:Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Abstract:In the presence of a manganese oxide based octahedral molecular sieve (OMS-2), a range of primary amides could be synthesized directly from primary alcohols and ammonia. The observed catalysis was heterogeneous, and the recovered catalyst could be reused many times without an appreciable loss of its catalytic performance.
Keywords:alcohols  amides  ammonia  heterogeneous catalysis  manganese oxide
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