Photoelectron emission spectroscopy of inorganic cations in aqueous solution |
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| Authors: | Paul Delahay Kathrin Von Burg Andrew Dziedzic |
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| Affiliation: | Department of Chemistry, New York University, New York, New York 10003, USA |
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| Abstract: | Threshold energies (6.1 <Et ? 8.6 eV) are determined for photoelectron emission by 16 inorganic cations in aqueous solution Et values are correlated with gas-phase ionization potentials, solvation and reorganization free energies, standard reduction potentials and ligand field stabilization energies (five transition metals). Dielectric saturation is shown to drastically lower threshold energies. |
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