Magnetic circular dichroism and molecular orbital studies on bicyclo[6,2,0] decapentaene |
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| Authors: | Akio Tajiri Masahiro Hatano Masaji Oda |
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| Affiliation: | Chemical Research Institute of Non-aqueous Solutions, Tohoku University Sendai 980, Japan;Department of Chemistry, Faculty of Science Tohoku University, Sendai 980 Japan |
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| Abstract: | The magnetic circular dichroism (MCD) spectrum of bicyclo[6,2,0] decapentaene has revealed four skeletal π → π* electronic transitions in the visible and ultraviolet region. The four MCD bands are assigned to the B2 ← A1, A1 ← A1. B2 ← A1 and A1 ← A1 electronic transitions in increasing order of energy. |
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