Pressure and temperature raman study of the rotational motion of propyne |
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| Authors: | T.W. Zerda S. Perry J. Jonas |
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| Affiliation: | Department of Chemistry, School of Chemical Sciences and Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801, USA |
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| Abstract: | The Raman line shapes in liquid propyne have been measured to obtain the rotational correlation times and rotational second moments. The correlation times are compared to the predictions of hydrodynamic model. The second moments aie shown to be density dependent. This effect is attributed to collision-induced scattering. |
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