Photoelectron emission spectroscopy of liquid water |
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| Authors: | Paul Delahay Kathrin Von Burg |
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| Affiliation: | Department of Chemistry, New York University, New York, New York 10003, USA |
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| Abstract: | The threshold energy Et = 10.06 eV (0.002 eV standard deviation) is determined for photoelectron emission by liquid water and is correlated with Et = 8.45 eV for OH? (aq). Free energy changes and standard reduction potentials are calculated for both emission processes. Reorganization free energies are correlated to solvation free energies for H2O+(aq) and OH?(aq). |
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