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An iets study of alumina and magnesia supported —sihx and their use as substrates for inorganic vibrational spectroscopy
Authors:Ursula Mazur  KW Hipps
Institution:Departments of Chemistry and Chemical Physics, Washington State University, Pullman, Washington 99164 USA
Abstract:Tunneling spectra of Al2O3/—SiHx, MgO/—SiHx, Al2O3/—SiDx, and Al2O3/—SiHx + NCS? are reported. Analysis of the vibrational spectra observed from isotopic substitution of the barriers obtained by deposition of a thin film of SiO onto alumina and magnesia indicate that the supported species is —SiH. The Al2O3/—SiH barrier can be used as a support for studying inorganic ions by IETS.
Keywords:To whom correspondence should be addressed  
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