| 双钼配合物氧化还原特性的研究 |
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| 引用本文： | 孙文涛,张致贵.双钼配合物氧化还原特性的研究[J].高等学校化学学报,1987,8(9):784. |
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| 作者姓名： | 孙文涛 张致贵 |
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| 作者单位： | 1. 长春冶金地质专科学校;
2. 吉林大学化学系 |
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| 摘 要： | 以MoCl5和二乙胺基硫代甲酸钠为原料,在AlCl3存在下于甲醇溶液中反应,生成双钼配合物MoS2CN(C2H5)2]+MoCl6]用循环伏安法研究了氧化还原特性。
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| 收稿时间： | 1986-02-28 |
A Study on the Oxidation-Reduction Characteristic of the Bimolybdenum Complex Compound |
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| Sun Wentao,Zhang Zhigui.A Study on the Oxidation-Reduction Characteristic of the Bimolybdenum Complex Compound[J].Chemical Research In Chinese Universities,1987,8(9):784. |
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| Authors: | Sun Wentao Zhang Zhigui |
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| Institution: | 1. Metallurgia Geologic Technical Colloge of Changchun, Changchun;
2. Department of Chemistry, Jilin University, Changchun |
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| Abstract: | The cyclic voltammogram of bimolybdenum complex compound is reported. It is shown that there are a pair of redox peaks and one reduction peak in the cyclic voltammogram. The results indicate that the redox peak pair is corresponding to the redox reaction of MoS2CN(C2H5)2]4+, which is semireversible, but another reduction peak is corresponding to the reduction reaction of MoCl6-, which is irreversible. |
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