Filament-breaking length—a measure of elasticity in extension

A technique has been developed to assess elasticity in extension of fluids which are weakly elastic. The technique is based on stretching a fluid sample held between two small closely spaced co-axial disks until the fluid bridge or filament breaks. The distance between the disks on breakup, ‘the breaking length’, is measured. When the fluid is elastic, this length is greater than that of an equivalent inelastic fluid. An inelastic baseline was established by measuring the breaking lengths of a wide variety of Newtonian fluids. Measurements with weakly elastic fluids reveal that the extra breaking length increases with polymer type and concentration and with the rate of stretching, the expected behavior for elastic liquids. The breaking lengths of model paper coatings were measured and found to correlate with the degree of misting in a roll coating machine, indicating that droplet formation is related to extensional elasticity.