Cross-coupling reactions of organosilicon compounds: new concepts and recent advances |
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Authors: | Denmark Scott Eric Sweis Ramzi Farah |
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Institution: | Department of Chemistry, University of Illinois, Urbana, Illinois 61801, USA. denmark@scs.uiuc.edu |
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Abstract: | This review highlights the rapid evolution of the newly-developed class of palladium-catalyzed cross-coupling reactions of organosilicon compounds. A myriad of heteroatom-containing silicon moieties (silyl hydrides, siletanes, silanols, silyl ethers, orthosiliconates, di- and polysiloxanes and pyridylsilanes) undergo mild and stereospecific cross-coupling. The diversity of methods for introduction of silicon groups into organic molecules and the range of organic electrophiles that can be used are emphasized. |
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