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硒脲及其衍生物的合成和应用
引用本文:李前进,杨春龙.硒脲及其衍生物的合成和应用[J].化学通报,2007,70(6):428-433.
作者姓名:李前进  杨春龙
作者单位:南京农业大学理学院化学系 南京210095
摘    要:硒脲及其衍生物具有抗真菌、抗肿瘤、抗癌等生物活性,可作为合成其它化合物的中间体和配体,还可用于增强显影剂的感光度。硒脲及取代硒脲的合成有取代脲法、氨腈法、异硒氰酸酯法等,缩氨基硒脲的合成有硒氰酸盐法和取代硫脲法,酰基硒脲的合成用常规法和相转移催化法。本文对硒脲及其衍生物的上述合成方法和应用作了介绍。

关 键 词:合成  硒脲  取代硒脲  缩氨基硒脲  酰基硒脲
修稿时间:2006-08-17

Synthesis and Applications of Selenourea and its Derivatives
Li Qianjin,Yang Chunlong.Synthesis and Applications of Selenourea and its Derivatives[J].Chemistry,2007,70(6):428-433.
Authors:Li Qianjin  Yang Chunlong
Institution:Department of Chemistry, College of Science, Nanjing Agricultural University, Nanjing 210095
Abstract:Selenourea and its derivatives possess the biological activities of anti-fungicide,anti-tumor,anticancer etc.,they can be used as intermediates and ligands to prepare other compounds and also be used to enhance the sensitization luminosity of the developers.They are synthesized by substituted ureas,cyanamides,isoselenocyanates,etc.,while selenosemicarbazones can be prepared by selenocyanates and substituted thioureas,and acylselenoureas have been obtained through the conventional method and the phase transfer catalysis method.In this paper,the syntheses and applications of selenourea and its derivatives were introduced.
Keywords:Synthesis  Selenourea  Substituted selenourea  Selenosemicarbazones  Acylselenoureas
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