| 1,8-萘酰亚胺修饰的卟啉及其作为F-识别化学传感器的研究 |
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| 引用本文： | 李扬,曹利峰,田禾.1,8-萘酰亚胺修饰的卟啉及其作为F-识别化学传感器的研究[J].化学通报,2007,70(2):151-154. |
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| 作者姓名： | 李扬 曹利峰 田禾 |
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| 作者单位： | 华东理工大学精细化工研究所教育部结构可控先进功能材料与制备重点实验室 上海200237 |
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| 基金项目： | 国家自然科学基金资助项目(20476027) |
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| 摘 要： | 合成了新型的具有识别F-能力的1,8-萘酰亚胺修饰的卟啉化合物,在F-的作用下,紫外-可见光谱和荧光光谱都发生明显的变化,而且可以被肉眼识别,该传感器可以作为具有F-选择性的比色和荧光化学传感器。
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| 关 键 词： | 氟离子 1 8-萘酰亚胺 卟啉 化学传感器 |
| 修稿时间： | 2006-10-24 |
The Synthesis of 1,8-Naphthalimides Functionalized Porphyrin and its Recognition of Fluoride Ion |
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| Li Yang,Cao Lifeng,Tian He.The Synthesis of 1,8-Naphthalimides Functionalized Porphyrin and its Recognition of Fluoride Ion[J].Chemistry,2007,70(2):151-154. |
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| Authors: | Li Yang Cao Lifeng Tian He |
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| Institution: | Labatory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237 |
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| Abstract: | A novel fluoride ion sensor based on 1,8-naphthalimides functionalized porphyrin was synthesized. In the presence of fluoride ion,both UV-Vis spectra and fluorescence spectra changed obviously,and such changes induced by the intermolecular proton transfer on N-H fragments are clearly visible to naked-eye. It is a good candidate for the colorimetric and fluorescence sensor for fluoride ion. |
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| Keywords: | Fluoride ion 1 8-Naphthalimide Porphyrin Sensor |
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