Synthesis of bismuth complexes from bismuth iodide and ammonium and phosphonium salts |
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| Authors: | V V Sharutin I V Egorova N N Klepikov E A Boyarkina O K Sharutina |
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| Institution: | (1) Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia |
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| Abstract: | The complexes Et2NH2] 3 + BiCl6]3? (I), NH4]+BiI4(C5H5N)2]?·2C5H5N (II), Ph3MeP] 2 + BiI5]2? (III), Ph3MeP] 2 + BiI5(C5H5N)]2?·C5H5N (IV), Ph3MeP] 3 + Bi3I12]3? (V), Ph3(i-Pr)P] 3 + Bi3I12]3?·2Me2C=O (VI), Ph3BuP] 2 + Bi2I8·2Me2C=O]2? (VII), and Ph3BuP] 2 + Bi2I8·2Me2S=O]2? (VIII) were obtained by reactions of bismuth iodide with ammonium and phosphonium iodides in acetone, pyridine, or dimethyl sulfoxide. |
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