| Synthesis and Structural Characterization of a Polyoxomolybdate HNa_7[Mo_(36)O_(112)(H_2O)_(16)]·47H_2O |
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| 引用本文： | LIU Ying② DOU Jian-Min WANG Da-Qi ZHANG Xian-Xi LI Da-Cheng JIA Ying-Chun (College of Chemistry and Chemical Engineering,Liaocheng University,Liaocheng 252059,China). Synthesis and Structural Characterization of a Polyoxomolybdate HNa_7[Mo_(36)O_(112)(H_2O)_(16)]·47H_2O[J]. 结构化学, 2007, 26(2): 165-171 |
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| 作者姓名： | LIU Ying② DOU Jian-Min WANG Da-Qi ZHANG Xian-Xi LI Da-Cheng JIA Ying-Chun (College of Chemistry and Chemical Engineering Liaocheng University Liaocheng 252059 China) |
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| 作者单位： | College of Chemistry and Chemical Engineering，Liaocheng University，Liaocheng 252059，China |
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| 基金项目： | The work was supported by NNSFC (No. 20501011)，Liaocheng University (31801) |
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| 摘 要： | A new polyoxomolybdate complex HNa7[Mo36O112(H2O)16]·47H2O 1 has been prepared in the beaker solution and characterized by single-crystal X-ray diffraction and elemental analyses. Crystal data: H127Mo36Na7O175, Mr = 6542.79, monoclinic, C2/c, a = 40.891(6), b = 17.900(3), c = 25.580(4) , β = 125.673(2)°, V = 15210(4) 3, Z = 4, Dc = 2.857 g/cm3, F(000) = 12464, μ = 3.013 mm-1, R = 0.0633 and wR = 0.1654 (I > 2σ(I)). With the bridging sodium cations, the [Mo36O112(H2O)16]8- units in compound 1 are linked to form a one-dimensional structure, on the basis of which a three-dimensional architecture is further constructed via other sodium cations and complicated hydrogen bonds.
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Synthesis and Structural Characterization of a Polyoxomolybdate HNa_7[Mo_(36)O_(112)(H_2O)_(16)]·47H_2O |
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| LIU Ying,DOU Jian-Min,WANG Da-Qi,ZHANG Xian-Xi,LI Da-Cheng,JIA Ying-Chun,. Synthesis and Structural Characterization of a Polyoxomolybdate HNa_7[Mo_(36)O_(112)(H_2O)_(16)]·47H_2O[J]. Chinese Journal of Structural Chemistry, 2007, 26(2): 165-171 |
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| Authors: | LIU Ying DOU Jian-Min WANG Da-Qi ZHANG Xian-Xi LI Da-Cheng JIA Ying-Chun |
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| Abstract: | A new polyoxomolybdate complex HNa7[Mo36O112(H2O)16]·47H2O 1 has been prepared in the beaker solution and characterized by single-crystal X-ray diffraction and elemental analyses. Crystal data: H127Mo36Na7O175, Mr = 6542.79, monoclinic, C2/c, a = 40.891(6), b = 17.900(3), c = 25.580(4) , β = 125.673(2)°, V = 15210(4) 3, Z = 4, Dc = 2.857 g/cm3, F(000) = 12464, μ = 3.013 mm-1, R = 0.0633 and wR = 0.1654 (I > 2σ(I)). With the bridging sodium cations, the [Mo36O112(H2O)16]8- units in compound 1 are linked to form a one-dimensional structure, on the basis of which a three-dimensional architecture is further constructed via other sodium cations and complicated hydrogen bonds. |
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| Keywords: | polyoxomolybdate molybdate sodium X-ray analysis |
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