Notes on selectivity aspects in sorbic acid and sorbic alcohol hydrogenation |
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Authors: | Eliška Leitmannová Radka Malá Libor Červený |
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Institution: | (1) Department of Organic Technology, Technicka 5, 166 28 Prague 6, Czech Republic |
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Abstract: | Sorbic acid and sorbic alcohol hydrogenations to the cis-hex-3-enoic acid or cis-hex-3-en-1-ol were carried out at the same conditions in three different systems—homogeneous, two-phase and heterogeneous.
The complex Cp*Ru(sorbic acid)]CF3SO3 was used as a catalyst. Selectivity and reactivity of both the compounds varied significantly. Using sorbic acid as a hydrogenation
substrate by-products were the other izomers of hexenoic acid and hexanoic acid, with sorbic alcohol as a hydrogenation substrate
by-products were aldehydes and hemiacetals. |
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Keywords: | Hydrogenation Ruthenium complex Sorbic acid Sorbic alcohol |
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