Solid-state mechanochemical synthesis of cobalt(III), iron(III), and chromium(III) bisdicarbollyl complexes |
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| Authors: | A. P. Borisov V. D. Makhaev A. Ya. Usyatinskii V. I. Bregadze |
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| Affiliation: | (1) Institute of New Chemical Problems, Russian Academy of Sciences, Chemogolovka, 142432 Moscow Region, Russian Federation;(2) Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | Thallous dicarbollide reacts with cobalt(II), iron(III) and chromium(III) chlorides without a solvent under conditions of mechanical activation to form the corresponding carborane complexes of tervalent metals. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1715–1717, October, 1993. |
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| Keywords: | mechanochemical synthesis dicarbollyl complexes |
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