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Additivity in kramers pairs symmetry: Multiplets with up to four unpaired electrons
Authors:Lukáš Bučinský  Michal Malček  Stanislav Biskupič
Affiliation:Institute of Physical Chemistry and Chemical Physics, Slovak University of Technology, Bratislava, Slovakia
Abstract:Many fermions Kramers pairs formalism is considered from the prospective of the sum of individual single fermion time‐reversal operators. The obtained many fermions “pseudo Kramers pairs operator” ( urn:x-wiley:00207608:media:qua25123:qua25123-math-0001), as well as its square ( urn:x-wiley:00207608:media:qua25123:qua25123-math-0002), have formally the same structure as the many fermion spin operators urn:x-wiley:00207608:media:qua25123:qua25123-math-0003 and urn:x-wiley:00207608:media:qua25123:qua25123-math-0004. Nevertheless, the shape of urn:x-wiley:00207608:media:qua25123:qua25123-math-0005 eigenfunctions with respect to urn:x-wiley:00207608:media:qua25123:qua25123-math-0006 and urn:x-wiley:00207608:media:qua25123:qua25123-math-0007 is different. Herein all Kramers adapted eigenfunctions of urn:x-wiley:00207608:media:qua25123:qua25123-math-0008 for cases of up to four unpaired fermions are compiled, and their properties with respect to urn:x-wiley:00207608:media:qua25123:qua25123-math-0009 further advocated. It will be shown that degeneracy of the urn:x-wiley:00207608:media:qua25123:qua25123-math-0010 multiplets recovers the proper behavior with respect to Pascal's triangle. A projection operator for obtaining the “high spin” Kramers adapted eigenfunctions is suggested. Noncommutation of urn:x-wiley:00207608:media:qua25123:qua25123-math-0011 with spin and angular momentum operators and degeneracy is discussed at last. © 2016 Wiley Periodicals, Inc.
Keywords:Kramers pair  time reversal  pseudo Kramers  Kramers adapted
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