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Retracted: A Facile Synthetic Route to New Fluorinated Building‐Blocks of 1‐Fluoroalkynes and 1‐Fluorodiynes
Authors:Cuibo Liu  Hai Ma  Jing Nie  Junan Ma
Institution:Department of Chemistry, Tianjin University, Tianjin 300072, China
Abstract:A facile and direct fluorination process of alkynes and diynes was developed. In the presence of n‐butyllithium, the reaction of a series of terminal alkynes and diynes with the electrophilic fluorinating reagent (NFSI) proceeded to afford various 1‐fluoroalkynes and 1‐fluoro‐1,3‐diynes in moderate to high yields.
Keywords:electrophilic fluorination  terminal alkyne  terminal 1  3‐diyne  1‐fluoroacetylene
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