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Synthesis,Characterization and Ion Exchange Properties of a New Composite of Inorganic Ion Exchanger: Polyacrylonitrile Cerium(IV) Molybdophosphate
Authors:Seyed Javad Ahmadi  Ramin Yavari  Parviz Ashtari  Vanik Gholipour  Leila Kamel  Farokh Rakhshandehru
Institution:1. Waste Management Department, Nuclear Science and Technology Research Institute, P. O. Box 11365/8486, Tehran, Iran;2. Faculty of Chemistry, Tarbiat Moallem University, P. C., Tehran, Iran
Abstract:In this work, the synthesis of the composite of cerium(IV) molybdophosphate (CMP) and polyacrylonitrile (PAN) was reported (CMP‐PAN). The material has been characterized by elemental and spectral (FT‐IR), X‐ray and thermal (TGA) analysis. Also the size analysis of the composite was done by scanning electron microscopy (SEM). Its chemical stability in acidic, basic and saline solutions and radiation stability up to 100 kGy total expose dose were assessed. Whereas the synthesized composite has ion exchange properties, its ion exchange capacity and behavior toward several metal ions were also investigated. Further, the distribution coefficients of the metal ions were calculated. Finally, the ability of the synthesized CMP‐PAN composite for the decontamination of low level liquid waste (LLLW) was investigated.
Keywords:composite  ion‐exchange  cerium(IV) molybdophosphate
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