Carbon-13 NMR studies of flavonoids—I : Flavones and flavonols |
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Authors: | B. Ternai K.R. Markham |
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Affiliation: | Chemistry Department, La Trobe University, Bundoora, Victoria, Australia 3083;Chemistry Division, D.S.I.R. Petone, New Zealand |
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Abstract: | 13C-NMR spectra of hydroxylated flavones and flavonols are presented for the first time. Analyses of the spectra are derived by consideration of a series of acetophenones, cinnamic acids, flavones and flavonols of increasing oxygenation pattern. The accepted substitution additivity rules have been shown to hold for these compounds except in cases where structural modifications involve the C-3,4 and 5 positions. |
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