Reverse Vesicles of Ferrum Laurate Metallosurfactant in Non‐Aqueous Solution Dried to Produce Solid Shells

Ferrum laurate [Fe(OOCC₁₁H₂₃)₃] metallosurfactant can successfully self‐assemble into reversed vesicles in organic media such as pure CHCl₃ and a mixed solvent of CHCl₃ and CH₃OH. Deformed solid vesicles, including collapsed erythrocyte‐like and broken hollow shells, were obtained directly by slectively drying the organic solvents. The morphology of the reversed vesicles of metallosurfactant in the organic media to hardly solid shells is maintained and it is ascribed to the evaporation rate of the solvents and the interactions between ferrum laurate and solvents.