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Catalytic,Mild, and Selective Oxyfunctionalization of Linear Alkanes: Current Challenges
Authors:Mélanie Bordeaux  Dr. Anne Galarneau  Dr. Jullien Drone
Affiliation:1. Institut Charles Gerhardt Montpellier, UMR 5253 CNRS/ENSCM/UM2/UM1, 8 rue de l'Ecole Normale, 34296 Montpellier (France);2. Ingénierie des Agropolymères et Technologies Emergentes, UMR 1208 SupAgro/INRA/CIRAD/UM2, 2 place Pierre Viala, 34060 Montpellier (France)
Abstract:Selective catalysts for sustainable oxidation of alkanes are highly demanded because of the abundance of these molecules in the environment, the possibility to transform them into higher‐value compounds, such as chemicals or synthetic fuels, and the fact that, kinetically speaking, this is a difficult reaction. Numerous chemical and biological catalysts have been developed in the lasts decades for this purpose, rendering the overview over this field of chemistry difficult. After giving a definition of the ideal catalyst for alkane oxyfunctionalization, this review aims to present the catalysts available today that are closest to ideal.
Keywords:biomimetic catalysts  cytochromes  green chemistry  methane monooxygenase  sustainable chemistry
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