Formation of Chiral Environments by a Mechanical Induced Vortex Flow |
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Authors: | Dr. Kunihiko Okano Prof.Dr. Takashi Yamashita |
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Affiliation: | Department of Pure and Applied Chemistry, 2641 Yamazaki, Noda‐hi, Chiba (Japan), Fax: (+81)?471241501 |
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Abstract: | A chiral molecule absorbs preferentially right‐ or left‐handed circularly polarized light in a circular dichroism (CD) measurement. Usually, the chirality of individual molecules is regarded as the origin of the CD signals. However, recently, several reports have suggested that the vortex flow of a solution of an achiral molecule gives rise to a CD signal, which is dependent on the stirring direction. This article introduces types of molecular architecture and material designs that show stir‐induced chirality. We also discuss the effects of the molecular structure and alignment in vortex flows on this phenomena, reviewing the related issues. |
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Keywords: | chirality circular dichroism self‐assembly supramolecular chemistry vortex flow |
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