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Stereoselective Total Synthesis of Stagonolide C |
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| Authors: | Jhillu S. Yadav Nimmakayala Mallikarjuna Reddy N. Venkateswar Rao Md. Ataur Rahman Attaluri R. Prasad |
| Affiliation: | 1. Organic Division‐I, Indian Institute of Chemical Technology, Hyderabad‐500007, India, (fax: +91‐40‐27160512);2. King Saud University, Riyadh‐11451, Saudi Arabia |
| Abstract: | A convergent and efficient total synthesis of stagonolide C ( 1 ), a phytotoxic metabolite, was achieved (Schemes 2 and 3) The synthesis exploited the high configuration control in the Prins cyclization along with alkene rearrangement and ring‐closing metathesis as key steps. |
| Keywords: | Stagonolide C Prins cyclization Alkene rearrangement Ring‐closing metathesis |