A neutral, monomeric germanium(I) radical |
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| Authors: | Woodul William D Carter Emma Müller Robert Richards Anne F Stasch Andreas Kaupp Martin Murphy Damien M Driess Matthias Jones Cameron |
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| Institution: | School of Chemistry, Monash University, P.O. Box 23, Clayton, Melbourne, VIC 3800, Australia. |
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| Abstract: | Stoichiometric reduction of the bulky β-diketiminato germanium(II) chloride complex ((But)Nacnac)GeCl] ((But)Nacnac = {N(Dip)C(Bu(t))}(2)CH](-), Dip = C(6)H(3)Pr(i)(2)-2,6) with either sodium naphthalenide or the magnesium(I) dimer {((Mes)Nacnac)Mg}(2)] ((Mes)Nacnac = (MesNCMe)(2)CH](-), Mes = mesityl) afforded the radical complex ((But)Nacnac)Ge:](?) in moderate yields. X-ray crystallographic, EPR/ENDOR spectroscopic, computational, and reactivity studies revealed this to be the first authenticated monomeric, neutral germanium(I) radical. |
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