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Symmetry of a molecule in an external field
Authors:A. V. Burenin
Affiliation:(1) Institute of Applied Physics, Russian Academy of Sciences, Nizhni Novgorod, 603950, Russia
Abstract:It is stated that, although an external field distorts a rigid molecule, it does not destroy internal geometric symmetry of its dynamics, which is specified by a point group. As a consequence, degeneracies of stationary states connected with this group are preserved. This statement makes it possible to describe the spectrum of a molecule in an external field based only on symmetry principles, which is exemplified by the linear Zeeman effect.
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