导电聚苯胺/橡胶复合材料的研究进展

聚苯胺是一种结构型导电高分子,因其特殊的结构和优异的物理化学性能,使它在二次电池、金属防腐、传感器、电容器、电磁屏蔽及抗静电等领域有着广泛而深入的应用前景。本文概述了导电聚苯胺的结构和特性,主要综述了聚苯胺/橡胶基复合材料的制备方法。其制备方法主要有共混法和聚合法,共混法主要有机械熔融共混法、溶液共混法和乳液共混法;聚合法主要包括电化学聚合、原位乳液聚合法、吸附聚合法等,总结了聚苯胺/橡胶基复合材料的研究情况及发展应用。

Research and Prospect of Conductive Polyaniline/rubber Composites

Polyaniline is a typical structural conducive polymer,because of its special structure and perfect physical chemistry properties,it can be widely used in secondary cell,metal protect,sensor,capacitor,electromagnetic shield and antistatic material,etc..The structure and property of conducive polyaniline are described in this paper.The two main methods introduced in this paper are blend which includes mechanical melt blending,solution blending and emulsion blending,and polymeriaztion which includes electrochemical polymeriaztion,situ emulsion polymeriaztion and adsorption polymerization.Developments and applications of conducive polyaniline/rubber composites are also introduced in this paper.