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Charge transfer chromophore-stopped [2]rotaxane through [2 + 2] cycloaddition
Authors:Zhou Weidong  Xu Jialiang  Zheng Haiyan  Liu Huibiao  Li Yuliang  Zhu Daoben
Institution:Beijing National Laboratory for Molecular Science, Chinese Academy of Sciences and Graduate school of Chinese Academy of Sciences, Beijing 100190, PR China.
Abstract:Three charge-transfer chromophore-terminated 2]rotaxanes were synthesized, using a high-yield 2 + 2]cycloaddition reaction in apolar solvent at room temperature. Two solvent-driving molecular shuttles were constructed, which exhibit distinct conformations in different solvent as a result of the shuttling movement of the macrocycle.
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