Arylation of adamantanamines: IV. Palladium-catalyzed arylation of amines of adamantane series with isomeric chloroquinolines |
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| Authors: | O K Grigorova A D Averin A S Abel O A Maloshitskaya V V Kovalev E N Savelev B S Orlinson I A Novakov I P Beletskaya |
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| Institution: | 1. Lomonosov Moscow State University, Moscow, 119991, Russia
2. Volgograd State Technical University, Volgograd, Russia
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| Abstract: | Palladium-catalyzed arylation of diverse amines of the adamantane series with isomeric chloroquinolines was investigated. The 2-chloroquinoline is the most reactive, however the best yields of the N-arylation products are most frequently obtained in the reaction with the less reactive 6-chloroquinoline. The applicability of the reaction is limited by the size of the substituent at the amino group. In some instances the noncatalytic amination of chloroquinolines was possible. |
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