| Synthesis and Crystal Structure of a New Coordination Polymer：{[AgL]ClO4}n （L=2,5-Bis（3-pyridinylmethylthio）-1,3,4-thiadiazole） |
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| 作者姓名： | XU Yan-Qing XIA Pei-Lei GAO Yuan-Zhe REN Ling HU Chang-Wen |
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| 作者单位： | Institute for Chemical Physics, Department of Chemistry, Beijing Institute of Technology, Beijing 100081, China |
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| 基金项目： | Supported by the National Natural Science Foundation of China （Nos. 20801004/1301, 20871016/130101, 10876002/A06）, the 111 Project （B07012）, and Excellent Young Scholars Research Fund of Beijing Institute of Technology （No. 2006Y0715） |
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| 摘 要： | The title complex {AgL]ClO4}n(L=2,5-bis(3-pyridinylmethylthio)-1,3,4-thiadiazole) was synthesized by the reaction of Ag(I) salt and a novel flexible ligand L.Its structure was determined by X-ray crystallography with the following data:monoclinic,space group P21/n,a=16.5068(13),b=7.6548(4),c=16.5521(13),β=115.119(3)o,V=1893.7(2)3,Z=4,Dc=1.893 g/cm3,μ=1.565 mm-1,F(000)=1072,C14H12AgClN4O4S3,Mr=539.78,T=293(2) K,S=1.067,the final R=0.0342 and wR=0.0870.The silver ion in the complex is in a trigonal coordination geometry to link three different L.Meanwhile,each L connects three different silver ions by its N coordination sites to form a two-dimensional layer structure.
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| 关 键 词： | 配位聚合物 联合集团 晶体结构 高氯酸 噻二唑 合成 X射线晶体学 银离子 |
Synthesis and Crystal Structure of a New Coordination Polymer：{[AgL]ClO4}n （L=2,5-Bis（3-pyridinylmethylthio）-1,3,4-thiadiazole） |
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| XU,Yan-Qing XIA,Pei-Lei GAO,Yuan-Zhe REN,Ling HU,Chang-Wen.Synthesis and Crystal Structure of a New Coordination Polymer：{[AgL]ClO4}n （L=2,5-Bis（3-pyridinylmethylthio）-1,3,4-thiadiazole）[J].Chinese Journal of Structural Chemistry,2010(2):191-194. |
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| Abstract: | The title complex {AgL]ClO4}n(L=2,5-bis(3-pyridinylmethylthio)-1,3,4-thiadiazole) was synthesized by the reaction of Ag(I) salt and a novel flexible ligand L.Its structure was determined by X-ray crystallography with the following data:monoclinic,space group P21/n,a=16.5068(13),b=7.6548(4),c=16.5521(13),β=115.119(3)o,V=1893.7(2)3,Z=4,Dc=1.893 g/cm3,μ=1.565 mm-1,F(000)=1072,C14H12AgClN4O4S3,Mr=539.78,T=293(2) K,S=1.067,the final R=0.0342 and wR=0.0870.The silver ion in the complex is in a trigonal coordination geometry to link three different L.Meanwhile,each L connects three different silver ions by its N coordination sites to form a two-dimensional layer structure. |
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| Keywords: | flexible ligand thioether-pyridine thiadiazole metallocycle X-ray structure |
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