| Synthesis and Crystal Structure of Bis[O,O'-di(2-phenylethyl)dithiophosphato](α,α'-bipyridine)copper(Ⅱ) |
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| 作者姓名： | ZOU Li-Ke XIE Bin ZHAO Bin FENG Jian-Shenb |
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| 作者单位： | [1]University Key Laboratory of Green Chemistry of Sichuan Province, Zigong 643000, China [2]Institute of Functionalized Materials, Sichuan University of Science ＆ Engineering, Zigong 643000, China [3]College of Chemistry andPharmaceutical Engineering, Sichuan University of Science ＆ Engineering, Zigong 643000, China [4]College of Material ＆ Chemical Engineering, Sichuan University of Science ＆ Engineering, Zigong 643000, China |
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| 基金项目： | supported by the Education Committee of Sichuan Province （No.09ZA057）; Department of Science and Technology of Sichuan Province （No. 2009JY0071 and 2010GZ0130）; Science and Technology Office of Zigong City （No. 08X01）; Key Laboratory of Material Corrosion and Protection of Sichuan Colleges and Universities （No. 2008CL04） |
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| 摘 要： | A ternary adduct Cu[S2P(OCH2CH2Ph)2]2·bipy(bipy=α,α'-bipyridine) was syn-thesized and characterized by elemental analysis,IR and single-crystal X-ray diffraction.The crystal belongs to the triclinic system,space group P1 with a=10.2320(2),b=11.5249(3),c=18.0916(3),α=98.95(1),β =103.601(1),γ=91.272(2)°,V=2044.49(7)3,Z=2,Dc=1.453 g/cm3,T=153(2) K,C42H44CuN2O4P2S4,Mr=894.51,λ(MoKα)=0.71073,μ=0.86 mm-1,S=0.999,(△/σ)max=0.002,the final R=0.0243 and wR=0.0704.A total of 9221 unique reflections were collected,of which 8573 with Ⅰ 2σ(Ⅰ) were observed.The Cu(Ⅱ) atom is five-coordinated in a rather distorted trigonal bipyramidal geometry(τ value=0.537).The Cu-S distances range from 2.3491(4) to 2.4829(4) ,and the Cu-N distances are 1.9987(12) and 2.0584(11) ,respectively.An interesting feature of this adduct resides in its two-dimensional(2D) open framework constructing through hydrogen bonding and π-π interactions.
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| 关 键 词： | 晶体结构 联吡啶 铜 合成 乙基 元素分析 射线衍射 三斜晶系 |
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