Novel Bi2O3 nanoporous film fabricated by anodic oxidation and its photoelectrochemical performance |
| |
Authors: | Xiaowei Lv Jianling Zhao Xixin Wang Xingru Xu Liyun Bai Buxue Wang |
| |
Institution: | 1. School of Material Science and Engineering, Hebei University of Technology, Guangrong Road, Tianjin, 300130, People’s Republic of China
|
| |
Abstract: | Novel bismuth oxide (Bi2O3) nanoporous films were fabricated through anodization of bismuth foil in electrolytes containing glycol, ammonium sulfate ((NH4)2SO4) and deionized (DI) water. Scanning electron microscopy analysis indicated that morphology of the anodized bismuth foil changed markedly along with the changing of oxidation time, water content, electrolyte concentration, temperature, and applied voltages. The optimized morphology was obtained when bismuth was anodized at 20 V, 40 °C for 40 min in glycol solution containing 0.3 wt% (NH4)2SO4 and 5 wt% DI water. The composition and crystal structure of the samples formed in the optimized conditions were characterized by energy-dispersive spectroscopy and X-ray diffraction. Results showed that the as-prepared nanoporous structures were amorphous. β-Bi2O3 was obtained when the samples were annealed at 200 °C. The photocurrent response experiments demonstrated that the Bi2O3 nanoporous film can generate photocurrent as large as 2.893 and 6.980 μA/cm2 under 0 and 0.5 V bias voltage versus saturated calomel electrode, respectively. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|