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Rapid method to determine 89/90Sr in steel samples
Authors:Maxwell  Sherrod L.  Culligan  Brian  Hutchison  Jay B.  Utsey  Robin C.  Sudowe  Ralf  McAlister  Daniel R.
Affiliation:1.Department of Chemistry, University of Helsinki, P.O. Box 55, 00014, Helsinki, Finland
;2.Radiochemistry Laboratory, School of Nuclear Science and Technology, Lanzhou University, Lanzhou, 73000, People’s Republic of China
;3.Geological Survey of Finland, Betonimiehenkuja 4, 02151, Espoo, Finland
;4.Posiva Oy, Olkiluoto, Finland
;
Abstract:

The sorption and diffusion behavior of cesium was studied to support the interpretation of the ongoing in-situ experiments in the Olkiluoto test site. The distribution coefficients of cesium in the Olkiluoto pegmatitic granite, veined gneiss and their main minerals were obtained by batch sorption experiments and the diffusion of cesium was studied in rock cubes. The results were modelled with PHREEQC and Comsol Multiphysics. The distribution coefficients of cesium were largest in biotite and veined gneiss. The effective diffusion coefficients of cesium from the diffusion model were 3 × 10−13 m2 s−1 for veined gneiss and 4 × 10−13 m2 s−1 for pegmatitic granite.

Keywords:
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