| A 2-D Copper Coordination Polymer [Cu(4,4''''-bpy)(H_2O)_4](C_4H_2O_4)(H_2O)_4 Integrated by Hydrogen Bonds and VDW Interactions |
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| 引用本文： | 康遥,李兆基,覃业燕,陈玉标,张健,胡瑞峰,温一航,程建开,姚元根. A 2-D Copper Coordination Polymer [Cu(4,4''''-bpy)(H_2O)_4](C_4H_2O_4)(H_2O)_4 Integrated by Hydrogen Bonds and VDW Interactions[J]. 结构化学, 2004, 23(8) |
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| 作者姓名： | 康遥 李兆基 覃业燕 陈玉标 张健 胡瑞峰 温一航 程建开 姚元根 |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
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| 基金项目： | This work was supported by the State Key Basic Research and Development Plan of China (001CB108906)，the NNSFC (No. 20173063) and NSF of Fujian Province (E0020001) |
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| 摘 要： | 1 INTRODUCTION A great deal of interest in transition metal com- plex assembly has recently been devoted to the development of rational synthetic routes to novel one-, two- and three-dimensional crystal frameworks, due to their potential applications in…
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A 2-D Copper Coordination Polymer [Cu(4,4''''-bpy)(H2O)4](C4H2O4)(H2O)4 Integrated by Hydrogen Bonds and VDW Interactions |
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| Abstract: | The title compound, [Cu(4,4-bpy)(H2O)4](C4H2O4)(H2O)4 1, has been syn- thesized by the reaction of Cu(NO3)23H2O with 4,4-bipyridine and fumaric acid, and structurally characterized by X-ray diffraction analysis. Its crystal structure belongs to monoclinic, space group C2/c with a = 16.6350(5), b = 11.1667(2), c = 13.1371(4) ? = 125.144(1) , C14H26CuN2O12, Mr = 477.91, Z = 4, V = 1995.47(9) 3, Dx = 1.591 g/cm3, m = 1.160 mm-1, F(000) = 996, R = 0.0331 and wR = 0.0883 for 1765 observed reflections (I > 2(I)). A two-dimensional network is formed in complex 1 through the hydrogen bonds and VDW interactions. |
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| Keywords: | copper 4 4?bipyridine fumaric acid a chain coordination polymer |
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