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35Cl NQR Studies of the Geometry of Aromatic Imines
Authors:G A Gartman  V A Glushkov  A D Gordeev
Institution:(1) Perm' State University, Perm'
Abstract:The preferred conformation of soliddashphase Rdash4dashbenzylidenedash3,4dashdichloroaniline molecules has been established by nuclear quadrupole resonance (NQR) combined with quantum chemical calculations. The conformational effect of substitutes reported previously is proved. The rotation angle of the plane of the aniline ring with respect to the plane of the azomethine bond is given.
Keywords:aromatic imines  conformational effect of substitutes  nuclear quadrupole resonance  quantum chemical calculations
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