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Simultaneous Removal of Surfactant Template from MCM—41 and Implantation of Transition Metal Complexes into Mesopores with Supercritical Fluid
引用本文:XiaoBingLU WenHuaZHANG 等. Simultaneous Removal of Surfactant Template from MCM—41 and Implantation of Transition Metal Complexes into Mesopores with Supercritical Fluid[J]. 中国化学快报, 2002, 13(5): 480-483
作者姓名:XiaoBingLU WenHuaZHANG 等
作者单位:[1]StateKeylaboratoryoffinechemicals,Dalianuniverstiyoftechnology,Dalian116012 [2]StateKeylaboratoryofCatalysis,Dalianinstituteofchemicalphysics,chineseAcademyofSciences,Dalian11602
摘    要:The simultaneous removal of up to 92% of the surfactant template and chemical implantation of transition metal complexes into mesopores has been successfully achieved by treating as-synthesized pure siliceous MCM-41 with supercritical CO2 modified with CH2Cl2/MeOH mixture,resulting in the formation of functionalized material with uniform pore structure.

关 键 词:表面活性剂 过渡金属络合物 超临界流体 MCM-41 中孔 间隙孔

Simultaneous Removal of Surfactant Template from MCM-41 and Implantation of Transition Metal Complexes into Mesopores with Supercritical Fluid
Xiao Bing LU,Wen Hua ZHANG,Ren HE. Simultaneous Removal of Surfactant Template from MCM-41 and Implantation of Transition Metal Complexes into Mesopores with Supercritical Fluid[J]. Chinese Chemical Letters, 2002, 13(5): 480-483
Authors:Xiao Bing LU  Wen Hua ZHANG  Ren HE
Abstract:The simultaneous removal of up to 92% of the surfactant template and chemical implantation of transition metal complexes into mesopores has been successfully achieved by treating as-synthesized pure siliceous MCM-41 with supercritical CO2 modified with CH2Cl2/MeOH mixture, resulting in the formation of functionalized material with uniform pore structure.
Keywords:MCM-41   mesoporous   supercritical fluids   transition metal complexes.
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